Chaos Origins (CORI) is the very first Core Booster of Series 14, the follow up to Blazing Dominion
In other words, whats the first Pokemon card? Is a different question than whats the first card with a Pokemon on it? If we are going to value a first appearance then honestly the video game is more of a correct answer First physical product to mention/depict Pocket Monsters
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By destroying an opponent's monster by battle, Goyo Guardian could special summon that monster to the player's side of the field