If you want to opt for a rarer mid-vintage set to open, this is probably the best option, thanks to the variety of other great hits in addition to the shiny Pokemon
Thassa's Oracle A format-warping card in competitive EDH, Thassa's Oracle is a merfolk who also happens to be one of the strongest alternative win cons in Magic: The Gathering
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1 Doctor Doom, King Of Latveria Doom Prevails Lead Commander My pick for the number one Commander of the Marvel Super Heroes precons is Doctor Doom, King of Latveria
A 4/4 card with Flying and Vigilance is still not one to dismiss outright though at a cost of 5 total mana, theres likely numerous other Angels, potentially cheaper in mana terms, that are better
A host of other cards have seen a ton of competitive play by shutting down the abilities of artifacts, including Null Rod, Stony Silence, Collector Ouphe, and Karn, the Great Creator