There are a handful that come to mind, from Palkia VSTAR to Kyogre from Crown Zenith
Whereas 151 had just 23 illustration rare and special illustration rare cards, for popular creatures like the starters and Legendary Pokmon, in Black Bolt and White Flare there are at least 156 cards of this rarity
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The Pokmon TCG: Scarlet & Violet : Paldea Evolved set has many valuable cards, some of which are very rare, but others are worth more money for other reasons